PTHH: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

Ta có: \(n_{H_2sO_4}=\dfrac{122,5\cdot40\%}{98}=0,5\left(mol\right)=n_{CuO}=n_{CuSO_4}\)

\(\Rightarrow\left\{{}\begin{matrix}m_{CuSO_4}=0,5\cdot160=80\left(g\right)\\m_{CuO}=0,5\cdot80=40\left(g\right)\end{matrix}\right.\)

\(n_{H_2}=\dfrac{2,464}{22,4}=0,11mol\)

\(\left\{{}\begin{matrix}Al:x\left(mol\right)\\Fe:y\left(mol\right)\end{matrix}\right.\Rightarrow Muối\left\{{}\begin{matrix}Al_2\left(SO_4\right)_3\\FeSO_4\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}BTe:3x+2y=2n_{H_2}=0,22\\\dfrac{x}{2}\cdot342+y\cdot152=14,44\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,04mol\\y=0,05mol\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,04\cdot27=1,08g\\m_{Fe}=0,05\cdot56=2,8g\end{matrix}\right.\)

\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow2AlCl_3+3BaSO_4\downarrow\)

0,02                                                   0,06

\(FeSO_4+BaCl_2\rightarrow BaSO_4\downarrow+FeCl_2\)

0,05                          0,05

\(\Rightarrow\Sigma n_{\downarrow}=0,06+0,05=0,11\Rightarrow m_{BaSO_4}=x=25,63g\)

\(n_{Al_2\left(SO_4\right)_3}=\dfrac{3,42}{342}=0,01mol\)

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

              0,03              0,01                      ( mol )

\(V_{H_2SO_4}=\left(\dfrac{0,03}{0,04}\right)+0,1=0,85l\)

a) Cu + 2H₂SO₄ → CuSO₄ + SO₂↑ + 2H₂O

\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

\(n_{SO_2}=n_{Cu}=0,2\left(mol\right)\)

\(\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)

\(\%m_{Cu}=\dfrac{12,8}{20,8}.100=61,54\%\); \(\%m_{CuO}=38,46\%\)

b) \(n_{CuO}=\dfrac{20,8-12,8}{80}=0,1\left(mol\right)\)

\(n_{H_2SO_4}=0,2.2+0,1=0,5\left(mol\right)\)

\(m_{ddH_2SO_4}=\dfrac{0,5.98}{80\%}=61,25\left(g\right)\)

\(n_{CuSO_4}=0,2+0,1=0,3\left(mol\right)\)

\(m_{CuSO_4}=0,3.160=48\left(g\right)\)

Giúp mình với, mình đang cần gấp

Câu 1 : 

\(n_{HCl}=\dfrac{73\cdot20\%}{36.5}=0.4\left(mol\right)\)

\(CuO+2HCl\rightarrow CuCl_2+H_2O\)

\(..........0.4.......0.2\)

\(m_{CuCl_2}=0.2\cdot135=27\left(g\right)\)

Câu 2 : 

\(n_{Fe_2O_3}=\dfrac{2.4}{160}=0.015\left(mol\right)\)

\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)

\(0.015...........................0.015\)

\(m_{dd}=2.4+300=302.4\left(g\right)\)

\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0.015\cdot400}{302.4}\cdot100\%=1.98\%\)

a)

Phần 1 : 

Gọi $n_{CuO} = a ; n_{Fe_2O_3} = b$

Ta có : 

$80a + 160b = 80 : 2 = 40(1)$
$CuO + 2HCl \to CuCl_2 + H_2O$
$Fe_2O_3 + 6HCl \to 2FeCl_3 + 3H_2O$

Suy ra:

$135a + 162,5.2b = 78,5(2)$
Từ (1)(2) suy ra a = 0,1 ; b = 0,2

$\%m_{CuO} = \dfrac{0,1.80}{40}.100\% = 20\%$
$\%m_{Fe_2O_3} = 80\%$

b)

Dung dịch muối gồm : 

$Fe^{3+} : 2b = 0,4(mol)$
$Cu^{2+} : a = 0,1(mol)$
$Cl^- : x(mol)$
$SO_4^{2-} : y(mol)$
Bảo toàn điện tích : 0,4.3 + 0,1.2 = x + 2y

$m_{muối} = 0,4.56 + 0,1.64 + 35,5x + 96y = 84,75$

Suy ra x = 0,9 ; y = 0,25

$C_{M_{HCl}} = \dfrac{0,9}{0,5} = 1,8M$
$C_{M_{H_2SO_4}} = \dfrac{0,25}{0,5} = 0,5M$

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

\(n_{H_2}=n_{Fe}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)

\(m_{CuO}=35.2-0.2\cdot56=24\left(g\right)\)

\(n_{CuO}=\dfrac{24}{80}=0.3\left(mol\right)\)

\(\%Fe=\dfrac{11.2}{35.2}\cdot100\%=31.82\%\)

\(\%CuO=100-31.82=68.18\%\)

\(n_{H_2SO_4}=0.2+0.3=0.5\left(mol\right)\)

\(m_{H_2SO_4}=0.5\cdot98=49\left(g\right)\)

\(C\%H_2SO_4=\dfrac{49}{800}\cdot100\%=6.125\%\)

\(m_{FeSO_4}=0.2\cdot152=30.4\left(g\right)\)

\(m_{CuSO_4}=0.3\cdot160=48\left(g\right)\)